Keywords:
Physical organic chemistry.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (353 pages)
Edition:
1st ed.
ISBN:
9781483219868
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1839195
Language:
English
Note:
Front Cover -- Anodic Oxidation -- Copyright Page -- Table of Contents -- Preface -- Part I: Principles and Methods -- Chapter 1. An Introduction to the Electrochemical Reaction -- I. Electrolysis and Its Terminology -- II. Faraday and the Laws of Electrolysis -- ΙII. How Is the Electric Current Carried through the Cell? -- IV. The Electrochemical Reaction-A Simple Picture -- V. A Most Important Factor-The Electrode Potential -- VI. The Origin and Significance of the Electrode Potential -- VII. The Sign of the Electrode Potential -- VIII. Thermodynamics of Electrode Potential -- IX. Reversiblity and Irreversibility -- X. The Electrical Double Layer -- XI. Adsorption at the Electrode-Solution Interface -- ΧII. A General Representation of an Electrochemical Reaction -- References -- Chapter 2. The Current-Potential Relationship -- I. The Rate of an Electrode Reaction-A Logical Place to Begin -- II. The Polarographic Method -- ΙII . Reactions under Activation-Controlled Conditions -- References -- Chapter 3. Other Electrochemical Methods -- I. Transient Behavior at the Electrode Surface -- II . Coulometric Studies and Preparative Methods -- References -- Chapter 4. The Electrochemical Reaction- Practical Aspects -- I. Cells and Circuits-The Two-Electrode Cell -- II . Cells and Circuits-The Three-Electrode Cell -- ΙII. Cells for Electrolysis -- IV. The Working Electrode -- V. Electrode Construction -- VI. The Counter or Auxiliary Electrode -- VII . Reference Electrodes in Aqueous Solutions -- VIII . Reference Electrodes in Nonaqueous Solutions -- IX. Solvents -- X. Supporting Electrolytes -- References -- Part II: A Survey of Anodic Oxidations -- Chapter 5. Hydrocarbons -- I. Introduction -- II. Substituted Benzenes -- ΙII. Anthracenes -- IV. Aryl Olefins -- V. Aliphatic and Alicyclic Hydrocarbons -- References.
,
Chapter 6. The Kolbe Acid Oxidation: Radical Reactions -- I. Introduction -- II. Experimental Conditions -- III. Side Reactions -- IV. Scope and Limitations -- V. Mechanism -- References -- Chapter 7. The Kolbe Acid Oxidation: Carbonium Ion Reactions -- References -- Chapter 8. Amines -- I. Aromatic Amines -- II. Aliphatic Amines -- References -- Chapter 9. Amides -- References -- Chapter 10. Hydrazines and Related Compounds -- I. Hydrazines -- II. Semicarbazides -- III. Hydrazones -- References -- Chapter 11. Alcohols and Phenols -- I. Alcohols -- II . Phenols -- References -- Chapter 12. Ethers -- I. Aliphatic Ethers -- II. Aromatic Ethers -- References -- Author Index -- Subject Index.
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