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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 109 (1997), S. 1995-1996 
    ISSN: 0044-8249
    Keywords: Bor ; Cluster ; Festkörperstrukturen ; Festphasensynthesen ; Selen ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1823-1832 
    ISSN: 0044-2313
    Keywords: Silver telluride ; stuetzite ; crystal structure ; tetrahedrally close-packed ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of Synthetic Stuetzite, Ag5-xTe3The crystal structure of Ag5-xTe3 was determined by single crystal X-ray structure analysis. The structure is of hexagonal symmetry (P 62m, Nr. 189) with a = 13.456(9) Å and c = 16.917(9) Å. The compound consists of highly mobile silver cations distributed in a tellurium framework forming Frank-Kasper polyhedra. Tellurium exists as Te2- as well as Te22--dumbbells and forms three types of tetrahedral sites. A description of the distribution of silver on the tetrahedral voids is given resulting in a suggestion of possible diffusion paths. Finally the homogenity region of Ag5-xTe3 is derived from the structure.
    Notes: Die Kristallstruktur von Ag5-x Te3 wurde durch Einkristall-Röntgenstrukturanalyse ermittelt. Die Struktur besitzt hexagonale Symmetrie (P62m, Nr. 189) mit a = 13,456(9) Å und c = 16,917(9) Å. Die Verbindung besteht aus beweglichen Silberkationen, die in einem Tellur-Gerüst von Frank-Kasper-Polyedern verteilt sind. Tellur liegt als Te2- und als Te22--Hantel vor und bildet drei verschiedene Arten von Tetraederlücken. Die Verteilung des Silbers auf die Tetraederlücken wird beschrieben. Daraus resultieren Vorschläge für mögliche Diffusionspfade. Schließlich wird der Homogenitätsbereich von Ag5-xTe3 aus der Struktur hergeleitet.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 1006-1010 
    ISSN: 0044-2313
    Keywords: Aluminium telluride ; crystal structure ; layer structures ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of β-Al2Te3The crystal structure of β-Ab2Te3 has been determined by means of single crystal x-ray diffractometry. The examined crystal can be described as a pseudomerohedric twin with a plane of reflection in (001) as twin element. The refinement in P21/c (No. 14) with the crystal parameters a = 7.181(1) Å, b = 12.848(3) Å. c = 14.167(3) Å, β = 90.04(2)°, V = 1307.1 Å3 and Z = 8 resulted in a final R-value (based on F) of 0.0245. β-Al2Te3 crystallizes in a layered arrangement and represents a new structure type.
    Notes: Die Kristallstruktur von β-Al2Te3 konnte auf der Grundlage von Einkristalldaten ermittelt werden. Der vermessene Kristall lag als pseudomeroedrischer Reflektionszwilling nach (001) vor. Die Verfeinerung in P21/c (Nr. 14) mit a - 7,181(1) Å, b = 12,848(3) Å, c = 14,167(3) Å, β = 90,04(2)°, V = 1307,1 Å3 und Z = 8 konvergierte gegen einen konventionellen R-Wert von 0,0245. β-Al2Te3 kristallisiert in einer Schichtstruktur und stellt einen neuartigen Strukturtyp dar.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 36 (1997), S. 1903-1904 
    ISSN: 0570-0833
    Keywords: boron ; clusters ; selenium ; solid-phase synthesis ; solid-state structures ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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