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  • Chemistry  (3)
  • Geology.  (2)
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  • 1
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Geology. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (295 pages)
    Edition: 1st ed.
    ISBN: 9783031082306
    DDC: 557.2921
    Language: English
    Note: Intro -- Preface -- Contents -- 1 Introduction -- 1.1 Introduction -- 1.2 Physiography of the Cayman Islands -- 1.3 Cayman Research-University of Alberta -- 1.4 Methods -- 1.4.1 Field Work and Drilling -- 1.4.2 Thin Sections -- 1.4.3 Scanning Electron Microscopy -- 1.4.4 X-Ray Diffraction Analysis -- 1.4.5 Electron Microprobe -- 1.4.6 Stable Isotope Analyses -- 1.4.7 87Sr/86Sr Analyses -- 1.4.8 Elemental and Rare Earth Elements -- 1.4.9 U/Th Dating -- References -- 2 Tectonic Setting of the Cayman Islands -- Abstract -- 2.1 Introduction -- 2.2 Earthquakes and Tsunamis -- 2.3 Tectonic Elements on the Cayman Islands -- 2.4 Conclusions -- References -- 3 Bluff Group-the Brac Formation -- Abstract -- 3.1 Introduction -- 3.2 Distribution -- 3.3 Lower Boundary -- 3.4 Upper Boundary -- 3.5 Thickness -- 3.6 Lithology -- 3.6.1 Cayman Brac -- Lepidocyclina Facies -- Mollusc Facies -- Foraminifera Facies -- Fabric Retentive Dolomite Facies -- Fabric Destructive Finely Crystalline Dolomite Facies -- Sucrosic Dolomite Facies -- 3.6.2 Grand Cayman -- 3.7 Porosity -- 3.8 Diagenesis -- 3.9 Dolomite Stoichiometry -- 3.10 Stable Isotopes -- 3.11 87Sr/86Sr Geochronology -- 3.12 Age -- 3.13 Depositional Regimes -- 3.14 Conclusions -- References -- 4 Bluff Group-The Cayman Formation -- Abstract -- 4.1 Introduction -- 4.2 Distribution -- 4.3 Lower Boundary -- 4.4 Upper Boundary -- 4.5 Thickness -- 4.6 Limestone-Dolostone Distribution -- 4.7 Biota -- 4.8 Facies -- 4.8.1 Grand Cayman -- 4.8.2 Cayman Brac -- 4.9 Depositional Regimes -- 4.10 Porosity and Permeability -- 4.11 Stable Isotopes -- 4.12 87Sr/86Sr Ratios -- 4.13 Age -- 4.13.1 Fossils -- 4.13.2 87Sr/86Sr Geochronology -- 4.13.3 Sea Level -- 4.14 Conclusions -- References -- 5 Bluff Group-Pedro Castle Formation -- Abstract -- 5.1 Introduction -- 5.2 Distribution -- 5.3 Lower Boundary -- 5.4 Upper Boundary. , 5.5 Thickness -- 5.6 Lithology -- 5.6.1 Grand Cayman -- 5.6.2 Cayman Brac -- 5.7 Stable Isotopes -- 5.8 Porosity and Permeability -- 5.9 87Sr/86Sr Geochronology -- 5.10 Age -- 5.11 Depositional Regimes -- 5.12 Conclusions -- References -- 6 Diagenesis-Bluff Group -- Abstract -- 6.1 Introduction -- 6.2 Dolostones of the Bluff Group -- 6.2.1 Dolomite Crystals -- Crystal Size -- Internal Structures and Compositional Zoning in Dolomite of the Cayman Islands -- Hollow Dolomite Crystals -- 6.2.2 Low and High Calcian Dolomite -- 6.2.3 Distribution of Low and High Calcian Dolomite -- Cayman Brac -- Grand Cayman -- 6.2.4 Stable Isotopes -- Brac Formation -- Cayman Formation -- Pedro Castle Formation -- 6.2.5 Trace Elements -- Na in Dolomite/Limestones -- Mn in Dolostones/Limestones -- Fe in Dolostones/Limestones -- Sr in Dolostones/Limestones -- Rare Earth Elements in Dolostones/Limestones -- 6.2.6 87Sr/86Sr Ratios -- Brac Formation -- Cayman Formation -- Pedro Castle Formation -- Modern Seawater -- Potential Problems with 87Sr/86Sr Ratios -- Brac Formation -- Cayman Formation and Pedro Castle Formation -- Comparison with Other Island Dolostones -- 6.3 Discussion -- 6.4 Conclusions -- References -- 7 Ironshore Formation -- Abstract -- 7.1 Introduction -- 7.2 Distribution -- 7.3 Lower Boundary -- 7.4 Upper Boundary -- 7.5 Thickness -- 7.6 Internal Stratigraphy -- 7.6.1 Lithological and Biological Characteristics of Units A to F -- 7.7 The 6 m Sea Level Notch -- 7.8 Key Exposures of the Ironshore Formation -- 7.8.1 Grand Cayman -- Salt Creek -- Canary Lane Quarry -- Boat Launch, Northwest Coast -- 7.8.2 Cayman Brac -- 7.8.3 Little Cayman -- Little Cayman Quarry -- Salt Rocks -- Unnamed Hill -- 7.9 Biota of the Ironshore Formation -- 7.9.1 Corals -- 7.9.2 Rhodolites -- 7.9.3 Stromatolites -- 7.9.4 Bivalves and Gastropods -- 7.10 Trace Elements. , 7.11 Diagenesis in the Ironshore Formation -- 7.11.1 Alteration of Skeletal Material -- Strombus Gigas Shells -- Corals -- 7.11.2 Calcretes -- 7.11.3 Rhizoliths -- 7.11.4 Roots and Caliche -- 7.11.5 Roots and Peloids -- 7.12 Conclusions -- References -- 8 Modern Carbonate Environments -- Abstract -- 8.1 Introduction -- 8.2 The Coastal Shelves of the Cayman Islands -- 8.3 Corals and Coral Reefs -- 8.3.1 Modern Corals of the Cayman Islands -- 8.3.2 Shelf-Edge Reef of Grand Cayman -- 8.4 Lagoons of Grand Cayman -- 8.4.1 North Sound -- The Fresh-Brackish Water Association -- The Marine Facies Association -- Rare Earth Elements -- Age -- Facies Architecture -- 8.4.2 South Sound -- Facies -- Age of Sediments -- Facies Changes Through Time -- Sedimentary Processes -- 8.4.3 Frank Sound and Pease Bay -- Facies -- Facies Changes Through Time -- Foraminifera in Frank Sound -- 8.4.4 East Sound -- 8.5 Bioerosion -- 8.6 Temporal Changes in Surface Seawater Temperatures -- 8.7 The Critical Role of Thalassia in the Lagoons of the Cayman Islands -- 8.8 Impact of Storms on the Coastal Areas of the Cayman Islands -- 8.8.1 Storm Boulders -- 8.8.2 Boulder Ramparts -- 8.8.3 Storm Impact on Lagoonal Sediments -- 8.9 Vermetid Buildups -- 8.10 Beachrock -- 8.11 Conclusions -- References -- 9 Karst on the Cayman Islands -- Abstract -- 9.1 Introduction -- 9.2 Modern Karst of the Cayman Islands -- 9.2.1 Phytokarst -- 9.2.2 Caves and Speleothems on Cayman Brac -- Caves in the Brac Formation -- Caves in the Cayman Formation -- Cave Speleothems -- Notch Speleothems -- 9.2.3 Caves and Speleothems on Grand Cayman -- The Twilight Zone -- Stalactites and Stalagmites -- Cave Pearls -- Calcite Versus Aragonite Precipitation -- Comparison of Notch Speleothems and Cave Speleothems -- 9.3 Vertebrate Fossils -- 9.4 Paleokarst on the Cayman Islands -- 9.4.1 Paleokarst Surfaces. , The Brac Unconformity -- The Cayman Unconformity -- The Pedro Castle Unconformity -- 9.5 Subsurface Paleokarst Features -- 9.5.1 Caymanite -- 9.5.2 Paleo-Caves -- 9.5.3 Sinkholes, Joints, and Other Cavities -- 9.6 Conclusions -- References -- 10 Terra Rossa, Phosphate, and Mangrove Swamps -- Abstract -- 10.1 Introduction -- 10.2 Terra Rossa -- 10.2.1 Stratigraphic Distribution of Lithified Terra Rossa on the Cayman Islands -- 10.2.2 Composition -- Clays, X-ray Amorphous Material, Anatase, Hematite, Goethite, and Manganese Precipitates -- Biofragments -- Glaebules -- Clay-Coated Grains and Terra Rossa Ooids -- Fractures -- 10.2.3 Stable Isotopes -- 10.2.4 Rare Earth Elements -- 10.2.5 Origin of Terra Rossa on the Cayman Islands -- 10.3 Phosphate Deposits -- 10.3.1 Composition of Phosphatic Limestone -- 10.3.2 Petrography of Phosphatic Limestones -- Lithoclasts and Detrital Phosphate Grains -- Glaebules -- Phosphate Rafts -- Matrix -- Microbes -- Calcite Cement -- 10.3.3 Stable Isotopes -- 10.3.4 Rare Earth Elements -- 10.3.5 Origin of Phosphate Deposits -- 10.4 Mangrove Deposits -- 10.4.1 Barkers Peninsula and West Bay Peninsula -- 10.4.2 Barkers Peninsula and West Bay Peninsula -- Laminated and Non-laminated Crusts -- Plastic Mud -- Peat -- 10.4.3 South Sound -- 10.4.4 Age and Development of Mangrove Swamps -- 10.5 Conclusions -- References -- 11 Hydrogeology -- Abstract -- 11.1 Introduction -- 11.1.1 Stage I -- 11.1.2 Stage II -- 11.1.3 Stage III -- 11.2 Bedrock Geology -- 11.3 Porosity and Permeability -- 11.4 Rainfall -- 11.5 Freshwater Lenses -- 11.5.1 Joints, Factures, and Water Lenses -- 11.5.2 Groundwater on the Cayman Islands -- Seawater -- Rainwater -- Pond Water -- Water in Sinkholes -- Cave Water -- Groundwater-Perched Water Zone -- Groundwater-Highly Brackish to Saline Water -- 11.5.3 Hydrochemical Facies -- Chloride Ions. , Bicarbonate Ions -- Calcium and Magnesium Ions -- 11.6 Groundwater Calcite and Dolomite Saturation States -- 11.6.1 Rainwater -- 11.6.2 Perched Water -- 11.6.3 Groundwater-Fresh Water Zone -- 11.6.4 Groundwater-Lightly Brackish Water Zone -- 11.6.5 Groundwater-Types I and II -- 11.7 Groundwater and Bedrock in and Around the East End Freshwater Lens -- 11.8 Development of Reverse Osmosis Plants -- 11.9 Conclusions -- References -- Appendix_1.
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  • 2
    Online Resource
    Online Resource
    Cham : Springer International Publishing | Cham : Imprint: Springer
    Keywords: Geology. ; Water. ; Hydrology. ; Sedimentology. ; Earth sciences. ; Geography. ; Große Antillen ; Cayman Islands ; Geologie ; Dolomit ; Diagenese ; Formation ; Karibik West ; Cayman Islands ; Kalkstein ; Karstlandschaft ; Gesteinskunde ; Geochemie ; Dolomitkalk ; Karsthöhle ; Karsthydrographie ; Carbonatgestein ; Grundwasser ; Hydrogeochemie ; Carbonatgestein ; Stratigraphie ; Hydrogeologie
    Description / Table of Contents: Introduction -- Tectonic Setting of Cayman Islands -- Stratigraphic framework -- The Bluff Group -- The Ironshore Formation -- Modern marine sediments of the Cayman Islands -- Dolomitization of the Bluff Group -- Karst and caves -- Phosphates, terra rossa and mangrove peat -- Modern Hydrology -- Summary Information Database.
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource(XIII, 291 p. 247 illus., 232 illus. in color.)
    Edition: 1st ed. 2022.
    ISBN: 9783031082306
    Language: English
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 15 (1992), S. 341-343 
    ISSN: 0935-6304
    Keywords: Capillary SFC ; Column coupling ; Restrictor ; Dead volume ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Microcolumn Separations 4 (1992), S. 215-220 
    ISSN: 1040-7685
    Keywords: retention index ; supercritical fluid chromatography ; selectivity ; temperature ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Retention indices (RI) for a variety of probe compounds were determined on 50-μm i. d. columns coated with eight different stationary phases under density programmed SFC conditions at isothermal temperatures of 80 and 150°C. RI values were strongly dependent on temperature for polar probes on the polar phases containing high levels of cyanopropyl or polyethylene glycol (PEG) functionality. A lower apparent polarity was observed for polar columns at higher temperatures. Moderate RI differences were apparent with the same probes on columns with polarizable stationary phases of high phenyl or biphenyl content. Nonpolar alkyl substituted stationary phases showed only a slight temperature dependence on RI for all test compounds. Alkanes of lower molecular weight eluted at lower densities on all columns when the temperature was raised because of the contribution of volatility to elution in SFC. This same effect was observed for the higher alkanes on both nonpolar and PEG columns, but they eluted at similar densities on cyanopropyl columns and at higher densities on columns with polarizable phases when the temperature was raised. Temperature controlled selectivity tuning is a useful tool in optimizing separations in SFC.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Microcolumn Separations 4 (1992), S. 221-225 
    ISSN: 1040-7685
    Keywords: Azo-t-butane ; cross-linking ; immobilization ; capillary columns ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The ability of commercially available azo-t-butun (ATB) to facilitate immobilization of polysiloxane stationary phases in capillary columns deteriorates upon storage. Aged ATB produces columns with high bleed, solute retention shifts, erratic immobilization efficiency, and high activity. This deterioration is accelerated in the presence of light, suggesting free radical processes are involved. The loss of certain lowlevel impurities, which act as free radical transfer agents or radical sinks, may be responsible for the performance change. Regeneration can often temporarily be accomplished using platinum catalyzed reduction with trichlorosilane. The addition of small amounts of toluene or other radical transfer agents to aged ATB moderates the cross-linking process, allowing the reproducible production of columns with good immobilization efficiency, excellent intertness, low thermal bleed, and proper polarity.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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