Publication Date:
2023-11-30
Description:
A novel and promising biomarker proxy for reconstruction of Arctic sea ice conditions was developed and is based on the determination of a highly branched isoprenoid with 25 carbons (IP25). IP25 records have been restricted to the last 150 kyr BP. We present a biomarker record from Ocean Drilling Program (ODP) Site 912, going back to the Pliocene–Pleistocene boundary and indicating that sea ice of variable extent occurred in the Fram Strait/southern Yermak Plateau area at least since about 2.2 Ma. Furthermore, our data support the idea that a combination of IP25 and open water, phytoplankton biomarker data (“PIP25 index”) may give a more reliable and quantitative estimate of past sea ice cover (at least for the study area). The study reveals that the novel IP25/PIP25 biomarker approach has potential for semi-quantitative paleo-sea ice studies covering the entire Quaternary and could motivate further detailed high resolution research on ODP/IODP material using this proxy.
Keywords:
(9E)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbon; (9Z)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbon; 151-912A; 151-912B; 2,10,14-Trimethyl-6-enyl-7-(3-methylpent-1-enyl)pentadecene, per unit mass total organic carbon; 2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyl)pentadecane, per unit mass total organic carbon; 24-ethylcholest-5-en-3beta-ol, per unit mass total organic carbon; 24-Methylcholesta-5,22E-dien-3beta-ol, per unit mass total organic carbon; AWI_Paleo; Calculated; Carbon, organic, total; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Element analyser CHN, LECO; Event label; Gas chromatography; Gas chromatography - Mass spectrometry (GC-MS); Joides Resolution; Leg151; Long-chain n-alkanes, C27+C29+C31, per unit mass total organic carbon; North Greenland Sea; Paleoenvironmental Reconstructions from Marine Sediments @ AWI; Phytoplankton biomarker Brassicasterol IP25 index; Sample code/label
Type:
Dataset
Format:
text/tab-separated-values, 170 data points
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