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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 199 (1998), S. 1581-1587 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The range of ADMET polymerization active catalysts has been expanded to include classical catalytic systems. The acyclic diene metathesis (ADMET) polymerization of hydrocarbon dienes has been performed using the aryloxy-tungsten complexes WCl4(O-2,6-C6H3Ph2)2 (4), W(O)Cl2(O-2,6-C6H3Br2)2 (5), and WCl4(O-2,6-C6H3Br2)2 (6) as the precatalytic species in combination with tetrabutyltin, tetramethyltin and tri-n-butyltin hydride as the cocatalytic entities. High molecular weight polyoctenylene and polyheptenylene are obtained under bulk polymerization conditions. The scope of these classical metathesis catalysts in the polymerization of other hydrocarbon as well as functionalized dienes is studied, revealing significant reactivity differences with respect to the previously studied well-defined metathesis catalysts and providing insights into the identification of suitable classical systems for ADMET polymerization.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2017-10-11
    Description: A biofertilizer (BF) based on the plant growth promoting rhizobacterium (PGPR) Bacillus siamensis was produced using anaerobic digestate (AD) as the main ingredient of the growth medium, alongside a carbon source from residual origin. The use of residues for the growth of PGPR reduces the production costs of biofertilizers, but makes an assessment of the possible toxicity of residues for the bacteria or plants necessary. Therefore, the growth medium of PGPR was first optimized using the response surface methodology (RSM), followed by phytotoxicity tests and a field trial of the BF in a sweet pepper ( Capsicum annuum L.) crop at two different locations. AD at 50% dilution, supplemented with 2.3% sugar beet molasses, was the optimum growth medium for producing the BF, with a bacterial concentration of 10 9 cfu mL −1 . In the field trial, the treatments inoculated with BF and fertilized with decreased mineral N (80%) produced significantly better yields per ha than the controls with decreased N (80%) and full N (100%) without BF. This indicates improved efficiency of N use by the crop, as a consequence of the use of BF.
    Print ISSN: 1436-8730
    Electronic ISSN: 1522-2624
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley-Blackwell
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  • 3
    Publication Date: 2011-07-20
    Description: This work describes the conformational behavior and the activation mechanism of timoprazole and substituted prazoles from the most stable conformation to the sulphenic acid. The stability of the conformers can be explained by the presence of hydrogen bonds, stereoelectronic effect because of the lone pair of sulfur atom and the N … C and N … S interactions. The first step of the Smile rearrangement is a nucleophilic addition to benzimidazole by pyridine moiety, which depends on the difference of the electron population of the atoms involved in the attack. The second step produces sulphenic acid by a concerted reaction where breaking of the S–C bond goes along with a proton migration, and is determined by the electron population of the sulfur atom. Copyright © 2011 John Wiley & Sons, Ltd. This work describes the conformational behavior and the activation mechanism of prazoles from the more stable conformation to the sulphenic acid the active molecule which inhibites the proton pump.
    Print ISSN: 0894-3230
    Electronic ISSN: 1099-1395
    Topics: Chemistry and Pharmacology , Physics
    Published by Wiley-Blackwell
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