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  • 1
    In: Royal Society Open Science, The Royal Society, Vol. 5, No. 6 ( 2018-06), p. 171811-
    Abstract: Hafnium-doped titania (Hf/Ti = 0.01; 0.03; 0.05) had been facilely synthesized via a template sol–gel method on carbon fibre. Physico-chemical properties of the as-synthesized materials were characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, energy-dispersive X-ray analysis, scanning transmission electron microscopy, X-ray photoelectron spectroscopy, thermogravimetry analysis and Brunauer–Emmett–Teller measurements. It was confirmed that Hf 4+ substitute in the Ti 4+ sites, forming Ti 1– x Hf x O 2 ( x  = 0.01; 0.03; 0.05) solid solutions with an anatase crystal structure. The Ti 1– x Hf x O 2 materials are hollow microtubes (length of 10–100 µm, outer diameter of 1–5 µm) composed of nanoparticles (average size of 15–20 nm) with a surface area of 80–90 m 2  g –1 and pore volume of 0.294–0.372 cm 3  g –1 . The effect of Hf ion incorporation on the electrochemical behaviour of anatase TiO 2 in the Li-ion battery anode was investigated by galvanostatic charge/discharge and electrochemical impedance spectroscopy. It was established that Ti 0.95 Hf 0.05 O 2 shows significantly higher reversibility (154.2 mAh g –1 ) after 35-fold cycling at a C /10 rate in comparison with undoped titania (55.9 mAh g –1 ). The better performance offered by Hf 4+ substitution of the Ti 4+ into anatase TiO 2 mainly results from a more open crystal structure, which has been achieved via the difference in ionic radius values of Ti 4+ (0.604 Å) and Hf 4+ (0.71 Å). The obtained results are in good accord with those for anatase TiO 2 doped with Zr 4+ (0.72 Å), published earlier. Furthermore, improved electrical conductivity of Hf-doped anatase TiO 2 materials owing to charge redistribution in the lattice and enhanced interfacial lithium storage owing to increased surface area directly depending on the Hf/Ti atomic ratio have a beneficial effect on electrochemical properties.
    Type of Medium: Online Resource
    ISSN: 2054-5703
    Language: English
    Publisher: The Royal Society
    Publication Date: 2018
    detail.hit.zdb_id: 2787755-3
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  • 2
    In: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, The Royal Society, Vol. 373, No. 2052 ( 2015-10-13), p. 20140451-
    Abstract: Sustained release of methane (CH 4 ) to the atmosphere from thawing Arctic permafrost may be a positive and significant feedback to climate warming. Atmospheric venting of CH 4 from the East Siberian Arctic Shelf (ESAS) was recently reported to be on par with flux from the Arctic tundra; however, the future scale of these releases remains unclear. Here, based on results of our latest observations, we show that CH 4 emissions from this shelf are likely to be determined by the state of subsea permafrost degradation. We observed CH 4 emissions from two previously understudied areas of the ESAS: the outer shelf, where subsea permafrost is predicted to be discontinuous or mostly degraded due to long submergence by seawater, and the near shore area, where deep/open taliks presumably form due to combined heating effects of seawater, river run-off, geothermal flux and pre-existing thermokarst. CH 4 emissions from these areas emerge from largely thawed sediments via strong flare-like ebullition, producing fluxes that are orders of magnitude greater than fluxes observed in background areas underlain by largely frozen sediments. We suggest that progression of subsea permafrost thawing and decrease in ice extent could result in a significant increase in CH 4 emissions from the ESAS.
    Type of Medium: Online Resource
    ISSN: 1364-503X , 1471-2962
    RVK:
    Language: English
    Publisher: The Royal Society
    Publication Date: 2015
    detail.hit.zdb_id: 208381-4
    detail.hit.zdb_id: 1462626-3
    SSG: 11
    SSG: 5,1
    SSG: 5,21
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