ISSN:
1572-9028
Schlagwort(e):
diboration
;
hydroboration
;
boron
;
platinum
;
rhodium
;
palladium
;
transition metal
;
homogeneous catalysis
;
boronate ester
;
arylboronate
;
vinylboronate
;
diboron
;
borylstannation
;
borylsilylation
;
silaboration
;
silicon
;
tin
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract Homogeneous transition metal catalysed hydroboration reactions are discussed briefly, providing the background which led to the recent discovery of metal catalysed diborations [additions of the B–B bond in B2(OR)4 compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and ά,βunsaturated ketones. Catalysed additions of B–Si and B–Sn bonds are also presented. Metal catalysed synthesis of organoboron compounds is a useful new synthetic method.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1019145818515
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