In:
Physical Chemistry Chemical Physics, Royal Society of Chemistry (RSC), Vol. 24, No. 18 ( 2022), p. 11066-11078
Abstract:
Pseudocapacitors offer both high energy and high power, making them suitable for grid-scale electrochemical energy storage to harness renewable energy produced from sun, wind, and tides. To overcome performance degradation in terms of cycling fading and lower specific capacitance values at high charge/discharge rates of electrochemical pseudocapacitors based on transition-metal oxides, perovskite-structured SrFeO 3− δ was envisaged as a negative electrode that harnesses the Fe 4+/3+ and Fe 3+/2+ redox couple to deliver superior performance. SrFeO 3− δ offers high specific capacitances of ca. 733 F g −1 at a scan rate of 1 mV s −1 and ca. 743 F g −1 at a current density of 1 A g −1 and demonstrates excellent cyclic stability over 2500 repeated cycles with capacitance retention of 〉 92%, achieving 94% coulombic efficiency. The good cycling stability is attributed to the inherent metallic electrical conductivity of SrFeO 3− δ and the fortuitous tendency of the robust cation framework structure to accommodate flexible oxygen content. The surface capacitive and diffusion-controlled contributions for capacitance are about ∼30% and ∼70%, respectively, at peak current and a scan rate equivalent to 1 mV s −1 . The higher capacitance and stable performance make SrFeO 3- δ an economical and abundant pseudocapacitive electrode.
Type of Medium:
Online Resource
ISSN:
1463-9076
,
1463-9084
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
1476283-3
detail.hit.zdb_id:
1476244-4
detail.hit.zdb_id:
1460656-2
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