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  • IOP Publishing  (2)
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  • IOP Publishing  (2)
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  • 1
    Online-Ressource
    Online-Ressource
    IOP Publishing ; 2022
    In:  Journal of Physics: Conference Series Vol. 2323, No. 1 ( 2022-08-01), p. 012030-
    In: Journal of Physics: Conference Series, IOP Publishing, Vol. 2323, No. 1 ( 2022-08-01), p. 012030-
    Kurzfassung: Nuclear magnetic resonance spectroscopy (NMR) probes using thin-film high temperature superconducting (HTS) resonators provide exceptional mass sensitivity in small-sample NMR experiments for natural products chemistry and metabolomics. We report improvements in sensitivity to our 1.5 mm 13 C-optimized NMR probe based on HTS resonators. The probe has a sample volume of 35 microliters and operates in a 14.1 T magnet. The probe also features HTS resonators for 1 H transmission and detection and the 2 H lock. The probe utilizes a 13 C resonator design that provides greater efficiency than our previous design. The quality factor of the new resonator in the 14.1 T background field was measured to be 4,300, which is over 3x the value of the previous design. To effectively implement the improved quality factor, we demonstrate the effect of adding a shorted transmission line stub to increase the bandwidth and reduce the rise/fall time of 13 C irradiation pulses. Initial NMR measurements verify 13 C NMR sensitivity is significantly improved while preserving detection bandwidth. The probe will be used for applications in metabolomics.
    Materialart: Online-Ressource
    ISSN: 1742-6588 , 1742-6596
    Sprache: Unbekannt
    Verlag: IOP Publishing
    Publikationsdatum: 2022
    ZDB Id: 2166409-2
    Standort Signatur Einschränkungen Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Online-Ressource
    Online-Ressource
    IOP Publishing ; 2020
    In:  Journal of Physics: Conference Series Vol. 1559, No. 1 ( 2020-06-01), p. 012022-
    In: Journal of Physics: Conference Series, IOP Publishing, Vol. 1559, No. 1 ( 2020-06-01), p. 012022-
    Kurzfassung: Nuclear magnetic resonance (NMR) probes using thin-film HTS coils offer high sensitivity and are particularly suitable for small-sample applications. Typically, HTS probes are optimized for the detection of multiple nuclei and require several coils to be located within a small volume near the sample. Coupling between the coils shifts coil resonances and complicates coil trimming when tuning HTS probes. We have modeled the magnetic coupling between the coils of a 1.5-mm all-HTS NMR probe with 13 C, 1 H, and 2 H channels. By measuring the magnetic coupling coefficients between individual coils, we solve the general coupling matrix given by KVL for six coupled resonators. Our results indicate that required trims can be accurately predicted by applying single coil trimming simulations to this magnetic coupling model. Use of the magnetic coupling model significantly improves the efficiency of tuning HTS probes.
    Materialart: Online-Ressource
    ISSN: 1742-6588 , 1742-6596
    Sprache: Unbekannt
    Verlag: IOP Publishing
    Publikationsdatum: 2020
    ZDB Id: 2166409-2
    Standort Signatur Einschränkungen Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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