Description: Although many of the regions on and close to the mid-ocean ridges have been extensively mapped and sampled, the abyssal intraplate regions remain essentially unsampled and unmapped, leaving huge gaps in our understanding of their geologic history and present activity. Prominent bathymetric features in these intraplate regions are fracture zones. Here we present bathymetric and sampling information from a transatlantic transect along the Vema Fracture Zone (ca. 11 °N), covering crustal ages from 109 − 0 Ma on the African plate and 0–62 Ma on the South American plate. The Vema Fracture Zone is the intraplate trace of the active Vema Transform plate boundary, which offsets the present-day Mid-Atlantic Ridge by ca. 300 km left-laterally, juxtaposing zero-age crust with crust of 20 million years age. Our results show clear evidence of tectonic activity along most of the Fracture Zone, in most places likely associated with active fluid flow. Within the active Vema Transform at crustal ages of ca. 10 Ma we found clear indications of fluid flow both in the sediments and the overlying water column. This region is 〉120 km from the nearest spreading axis and increases by almost an order of magnitude the maximum off-axis distance that active hydrothermal discharge has been found in the oceanic crust. Sampling of the igneous seafloor was possible at all crustal ages and the accretionary fabric imprinted on the plate during its production was prominent everywhere. Seafloor sediments show signs of extensive bioturbation. In one area, high concentrations of spherical Mn-nodules were also found and sampled. At the end of the transect we also mapped and sampled the Puerto Rico Trough, a 〉8000 m deep basin north of the Caribbean arc. Here the seafloor morphology is more complicated and strongly influenced by transpressive tectonics.

Description: Highlights • Formation of Axial Volcanic Ridges is more complex than previous models suggest. • Faults on the Reykjanes Ridge strike orthogonal to spreading direction. • Seamounts and fault densities reflect volcanic robustness of Axial Volcanic Ridges. • Steinahóll Vent Field occupies shallow eruptive fissure located between two faults. Abstract Current estimates indicate that the number of high-temperature vents (one of the primary pathways for the heat extraction from the Earth's mantle) – at least 1 per 100 km of axial length – scales with spreading rate and should scale with crustal thickness. But up to present, shallow ridge axes underlain by thick crust show anomalously low incidences of high-temperature activity. Here we compare the Reykjanes Ridge, an abnormally shallow ridge with thick crust and only one high-temperature vent known over 900 km axial length, to the adjacent subaerial Reykjanes Peninsula (RP), which is characterized by high-temperature geothermal sites confined to four volcanic systems transected by fissure swarms with young (Holocene) volcanic activity, multiple faults, cracks and fissures, and continuous seismic activity. New high-resolution bathymetry (gridded at 60 m) of the Reykjanes Ridge between 62°30′N and 63°30′N shows seven Axial Volcanic Ridges (AVR) that, based on their morphology, geometry and tectonic regime, are analogues for the volcanic systems and fissure swarms on land. We investigate in detail the volcano-tectonic features of all mapped AVRs and show that they do not fit with the previously suggested 4-stage evolution model for AVR construction. Instead, we suggest that AVR morphology reflects the robust or weak melt supply to the system and two (or more) eruption mechanisms may co-exist on one AVR (in contrast to 4-stage evolution model). Our interpretations indicate that, unlike on the Reykjanes Peninsula, faults on and around AVRs do not cluster in orientation domains but all are subparallel to the overall strike of AVRs (orthogonal to spreading direction). High abundance of seamounts shows that the region centered at 62°47′N and 25°04′W (between AVR-5 and -6) is volcanically robust while the highest fault density implies that AVR-1 and southern part of AVR-6 rather undergo period of melt starvation. Based on our observations and interpretations we expect all of the AVRs on Reykjanes Ridge to be hydrothermally active but morphological and hydrographic settings of this ridge may cause hydrothermal plumes to be quickly dispersed and diluted due to exposure to strong bottom currents. Therefore, combined CTD and autonomous vehicles surveys are probably the most efficient methods for hydrothermal exploration along the Reykjanes Ridge.

Description: The upper oceanic crust is produced by magmatism at mid-ocean ridges, a process thought to be characterized by cyclic bouts of intense magmatic activity, separated by periods when faulting accommodates most or even all of the plate motion. It is not known whether there is a distinct periodicity to such magmatic–tectonic cycles. Here we present high-resolution sidescan sonar data from the neovolcanic zone of the North Kolbeinsey Ridge, a shallow slow-spreading ridge where high glacial and steady post-glacial sedimentation rates allow relative flow ages to be determined with a resolution of around 2 kyrusing backscatter amplitude as a proxy for sediment thickness and hence age. We identify 18 lava flow fields covering 40% of the area surveyed. A group of 7 flowfields showing the highest (and similar) backscatter intensity are scattered along 75 km of axial valley surveyed, suggesting that at least this length of the segment was magmatically active within a 1.2 kyrtime window. Based on conservative age estimates for all datable flows and estimated eruption volumes, the post-glacial volcanic activity imaged is insufficient to maintain crustal thickness, implying that episode(s) of enhanced activity must have preceded the volcanism we image.

Description: Highlights • Hydrothermalism in off-axis Tertiary Iceland crust is low-temperature (〈 100 °C). • Hydrothermalism is dike-controlled, unlike the fault-hosted venting in on-axis areas. • Inactive off-axis faults seal quickly due to fluids reacting with fine-grained gouge. • Cracks in country rock next to the dikes form major vertical off-axis permeability. • We predict locations of venting in off-axis regions (〉 2 Ma) of the Reykjanes Ridge. Abstract Hydrothermal activity along the Mid-Atlantic Ridge is predominantly high-temperature venting controlled by volcano-tectonic processes confined to the ridge axis and neotectonic zone, which extends ~ 20 km on each side of the axis (e.g. TAG or Logatchev 1). These vents cannot, however, account for all the heat which needs to be removed to cool the plate and a significant amount of heat is probably removed in the off-axis regions as well. These regions have previously not been systematically surveyed for hydrothermal activity due to a lack of predictive models for its nature, location or controlling structures. Here we use hot springs in the Tertiary Westfjords of Iceland as onshore analogs for hydrothermal activity along the off-axis Mid-Atlantic Ridge to better understand tectonic and volcanological controls on their occurrence, as well as the processes which support hydrothermal circulation. Our results show that even crust ≥ 10 Ma has abundant low-temperature hydrothermal activity. We show that 66% of hot springs investigated, and 100% of those for which a detailed geological setting could be determined, are associated with basaltic dikes cross-cutting the sub-horizontal lava sequence. This is in strong contrast to on-axis springs, which are known (both from underwater and on land) to be predominantly associated with faults. Absence of earthquakes in Westfjords suggests that the faults there are no longer active and possibly sealed by secondary minerals, suppressing fluid circulation. In such a situation, the jointed and fractures dike margins may provide the major pathways for fluid circulation. Extrapolating this idea to the off–axis regions of the Reykjanes Ridge, we suggest, based on bathymetric maps, potential sites for future exploration for off-axis hydrothermal systems.

Description: U-series disequilibria have provided important constraints on the physical processes of partial melting that produce basaltic magma beneath mid-ocean ridges. Here we present the first 238U–230Th–226Ra isotope data for a suite of 83 basalts sampled between 5°S and 11°S along the South Mid-Atlantic Ridge. This section of the ridge can be divided into 5 segments (A0–A4) and the depths to the ridge axis span much of the global range, varying from 1429 to 4514 m. Previous work has also demonstrated that strong trace element and radiogenic isotope heterogeneity existed in the source regions of these basalts. Accordingly, this area provides an ideal location in which to investigate the effects of both inferred melt column length and recycled materials. 226Ra–230Th disequilibria indicate that the majority of the basalts are less than a few millennia old such that their 230Th values do not require any age correction. The U–Th isotope data span a significant range from secular equilibrium up to 32% 230Th excess, also similar to the global range, and vary from segment to segment. However, the (230Th/238U) ratios are not negatively correlated with axial depth and the samples with the largest 230Th excesses come from the deepest ridge segment (A1). Two sub-parallel and positively sloped arrays (for segments A0–2 and A3 and A4) between (230Th/238U) and Th/U ratios can be modelled in various ways as mixing between melts from peridotite and recycled mafic lithologies. Despite abundant evidence for source heterogeneity, there is no simple correlation between (230Th/238U) and radiogenic isotope ratios suggesting that at least some of the trace element and radiogenic isotope variability may have been imparted to the source regions 〉350 kyr prior to partial melting to produce the basalts. In our preferred model, the two (230Th/238U) versus Th/U arrays can be explained by mixing of melts from one or more recycled mafic lithologies with melts derived from chemically heterogeneous peridotite source regions.

Description: Highlights • Hydrothermal survey in the 13°-33°S region of the Mid-Atlantic Ridge based on hydrographic casts, noble gas observations and AUV dives. • Discovery of hydrothermal plumes above ten ridge segments pointing to 14 unknown active vent sites. • Rio de Janeiro Transform (22°S) likely represents a barrier separating different vent endemic faunal communities to the north and south. Abstract The oceanic crust is initially cooled and deep-sea chemosynthetic ecosystems are largely fed by hydrothermal circulation and venting on the seafloor. Much of this venting takes place at mid-ocean ridges and in order to make realistic models of the crust's thermal budget and to understand chemosynthetic biogeography it is important to have a detailed inventory of vent sites. Until recently, a major gap in this inventory was the Mid-Atlantic Ridge south of 13°S, a key region for vent fauna biogeography as it is the corridor linking the Atlantic to the Indian and Pacific Oceans. In spring 2013 we systematically surveyed the axial region between 13°S and 33°S for hydrothermal signals in the water column, using turbidity, oxidation-reduction-potential (ORP) and noble gases as indicators. Standard conductivity-temperature-depth (CTD) rosette water-sampler deployments were complimented by a novel autonomous underwater vehicle (AUV) deployment strategy, in which the AUV made single-pass, segment-scale (up to 100 km long) dives close to the seafloor to detect small vents. The ca. 2100 km-long survey covered 16 ridge segments and we identified previously unknown hydrothermal plumes above ten segments that point to 14 new hydrothermal vent fields. The majority of plumes are located at high-relief segment centers, where magmatism is robust. A wide gap in the distribution of vents in the 19°S-23°S region coincides with the Rio de Janeiro Transform, the maximum southward progression of North Atlantic Deep Waters and the maximum northwards extent of 3He-enriched waters with Pacific origins. Crossflowing currents in the transform and the large gap between adjacent vents may prevent a meridional connection between the vent fauna communities in the North Atlantic and along the Antarctic Ridges. This makes the region a prime target for future biogeographical studies.

Description: Highlights • Generic geological model of hydrothermally extinct seafloor massive sulphide. • Sub-surface characterisation by combined drilling and geophysics. • New resource estimate for slow-spreading mid-ocean ridges. • Holistic approach to seafloor mineral deposits assessment. Abstract Deep-sea mineral deposits potentially represent vast metal resources that could make a major contribution to future global raw material supply. Increasing demand for these metals, many of which are required to enable a low-carbon and high-technology society and to relieve pressure on land-based resources, may result in deep sea mining within the next decade. Seafloor massive sulphide (SMS) deposits, containing abundant copper, zinc, gold and silver, have been the subject of recent and ongoing commercial interest. Although many seafloor hydrothermally systems have been studied, inactive SMS deposits are likely to more accessible to future mining and far more abundant, but are often obscured by pelagic sediment and hence difficult to locate. Furthermore, SMS deposits are three dimensional. Yet, to date, very few have been explored or sampled below the seafloor. Here, we describe the most comprehensive study to date of hydrothermally extinct seafloor massive sulphide deposits formed at a slow spreading ridge. Our approach involved two research cruises in the summer of 2016 to the TAG hydrothermal field at 26°N on the Mid-Atlantic Ridge. These expeditions mapped a number of hydrothermally extinct SMS deposits using an autonomous underwater vehicle and remotely operated vehicle, acquired a combination of geophysical data including sub-seafloor seismic reflection and refraction data from 25 ocean bottom instruments, and recovered core using a sub-seafloor drilling rig. Together, these results that have allowed us to construct a new generic model for extinct seafloor massive sulphide deposits that indicate the presence of up to five times more massive sulphide at and below the seafloor than was previously thought.

Description: Highlights • Decoupling of volatile element enrichment and magmatic volatile influx. • Multiple sulfide generations with distinct trace element signatures. • Boiling-induced pyrite precipitation revealed by textures and Tl/Pb, Sb/Pb and Bi/Pb ratios. • Boiling-induced Au, electrum and Bi-telluride colloids lead to high Au grades. • Metals sources: shallow upflow- (60–80%) and deep reaction (20–40%) zone. Abstract Shallow (〈1500 mbsl) submarine arc-related hydrothermal systems can host base (Cu), precious (Au) and volatile elements (As, Se, Sb, Te, Tl) in significant quantities. Their wide application in the high-tech industry, but a potential eco-toxicological footprint gives them a strategic importance. However, the processes that concentrate these elements in submarine arc-related hydrothermal systems, compared to their mid-ocean ridge counterparts are still debated, and it is unclear whether boiling-related processes and/or the contribution of magmatic volatiles are key for their enrichment. We present bulk sulfide-sulfate, isotope (S and Pb), and high-resolution microanalytical data of hydrothermal sulfides from the Niua South fore-arc volcano in north Tonga, where numerous black-smoker type sulfide-sulfate chimneys emit boiling fluids with temperatures (up to 325 °C) near the seawater boiling curve at ~1170 m water depth. Hence, this system represents an ideal natural laboratory to investigate the effect of fluid boiling on base, precious, and volatile element enrichment associated with hydrothermal seafloor mineralization. At Niua South, textural and chemical variations of multiple pyrite (framboidal, euhedral and massive), chalcopyrite (linings), and sphalerite (dendrites and linings) generations are indicative for sulfide precipitation from early low-temperature (~240 °C) fluids that underwent abundant mixing with ambient seawater (low Se/Tl and Co/Ni ratios in pyrite) and from later high-temperature (up to 325 °C) (high Se/Tl and Co/Ni ratios in pyrite). In addition, crustiform inclusion-rich pyrite that precipitated from high-temperature boiling fluids shows low Bi/Pb, Tl/Pb and Sb/Pb ratios due to volatile element loss (e.g., Tl and Sb) to the vapor phase compared to pyrite that formed during the low temperature stage. By contrast, late sphalerite (~280 °C) is enriched in elements with an affinity to Cl-complexes like Mn, Co, Ni, Ga, Cd, In, and Sn, and therefore precipitated from the corresponding Cl-rich liquid phase. Gold occurs in solid-solution and as boiling-induced particles of native Au, electrum, and Au-rich Bi-tellurides in pyrite (up to 144 ppm Au), sphalerite (up to 60 ppm Au), and chalcopyrite (up to 37 ppm Au). These particles (〈5–10 µm) probably formed during fluid boiling causing an extreme Au enrichment (〉30 ppm) in the mature and late stage of chimney formation. Lead isotope data indicate that the hydrothermal fluids scavenged metals not only from the deeper basement in the reaction zone (20–40%), but also from young dacitic volcanic rocks near the seafloor in the upflow zone (60–80%). Sulfur isotope (δ34S = −0.3 to 4.4‰) and Se/S*106 values (〈1500) of hydrothermal sulfides provide no evidence for a magmatic volatile influx and indicate that S, and most metals and semi-metals were likely leached from the host rocks. Hence, volatile (As, Se, Sb, Te, Tl), and precious (Au) element enrichments in arc-related submarine hydrothermal systems can be decoupled from magmatic volatiles and are instead a result of boiling-induced trace element fractionation – a hydrothermal enrichment process, which has been underestimated to date.

Description: Highlights • Evidence for young volcanism has been found on 20Ma oceanic crust in the Peru Basin. • This volcanism appears unrelated to hotspot or petit-spot activity and as such represents a new type of intraplate volcanism. • The volcanism may be linked to seismically slow shallow mantle beneath the Nazca plate. • Intraplate tension does not seem to be the trigger for the volcanism. The abyssal plains are generally assumed to be geologically inactive parts of the ocean plate interiors where processes (such as pelagic sedimentation or manganese crust and nodule formation) occur at very slow rates. In terms of intraplate volcanic activity, almost all is assumed to occur at hotspots, leading to little exploration in other intraplate regions. The Peru Basin is an abyssal plain known to host Mn-nodule fields. We present remotely-operated underwater vehicle (ROV) investigations of a small seamount adjacent to such a Mn-nodule field on 20Ma Nazca Plate crust, showing that it appears to have been recently volcanically and hydrothermally active. The seamount lies 1600km east of the nearest spreading axis (East Pacific Rise) and 600km from both the Galapagos Plateau (to the north) and the subduction zone off Peru (to the east), making off-axis, hotspot or petit-spot processes unlikely as a cause of the volcanism. The shallow mantle below the Nazca (and conjugate Pacific) Plate shows globally anomalous low seismic shear-wave velocities, perhaps reflecting higher-than-normal amounts of melt in the mantle below this region which may provide a source for the magmas. Our own regional mapping work and literature sources highlight several similar sites of probable young volcanism elsewhere in the Peru Basin which may also be related to this anomaly. The Nazca abyssal plain may be much more geologically active than previously thought. If so, this could have wider implications for, among other things, chemosynthetic ecosystem connectivity.