Description: Long-term observations of the deep ocean particle flux from three sites in the northeast Atlantic (33 degrees N, 22 degrees W; 47 degrees N, 20 degrees W; 54 degrees N, 20 degrees W) provide the basis for comparison and characterization of the biogeochemical provinces in terms of sedimentation pattern. Deep ocean particle flux data (2000 in) for fluxes of total mass and the flux composition are presented and compared to published sediment trap data from this area to consider regional-scale variations in the quantity and composition of settling material. The observations show that in the northeast Atlantic gradient of decreasing mass flux from North to South, exists consistent with known changes of biological productivity in surface waters. This gradient is associated with similar trends in opal and particulate organic carbon, whereas calcium carbonate shows trend in the opposite direction. The changes in the composition of the settling material found along the transect are indicating that the calcium carbonate flux is critical in removing organic matter from the upper ocean to the deeper sink. Its role declines from the subtropical ocean (60-80% of the particle flux) towards North (〈 40%) reflecting the decreasing importance of coccolithophorid/foraminiferal blooms for particle flux from the subtropical to the subpolar North Atlantic. In contrast, the role of biogenic silica (opal) in regard to the ballasting effect increases towards North. The northern sites have much higher percentage of biogenic silica than the sites in the South, because of the deep winter mixing and the seasonality of phytoplankton dominated by diatom blooms during spring and summer. The comparison of the seasonal pattern of particle flux with the seasonal pattern of surface chlorophyll a concentrations from SeaWiFS together with the similarity of the pattern observed in calcium carbonate and opal leads to the conclusion that the particle flux at two positions (33 degrees N, 22 degrees W; 47 degrees N, 20 degrees W) is fast and directly coupled to the phytoplankton dynamics in the overlying euphotic zone.

Description: The effect of the supply of chlorinated biphenyls by the river Oder into some adjacent areas of Baltic Sea was studied in nine sediment cores and in 10 suspended matter samples. Congener-specific analysis was carried out on 28 individual chlorobiphenyls (CBs). ∑CB concentrations in suspension ranged from 2.4 pg dm-3 in the southern Bornholm Basin to 986 pg dm-3 in the Achterwasser. ∑CB contents in surface sediment decreased with increasing distance from the river mouth. Highest contents were found in the Oderhaff (18 ng g-1 dw) decreasing to 2 ng g-1 dw in the Bornholm Basin. The ∑CB contents generally decreased more or less regularly with increasing depth. The compositions of the CB mixtures in surficial sediment and suspension samples were rather similar, suggesting a common source. Compositions of the CB mixtures in the sediment cores showed distinct differences. These may reflect variations in source strength over time. Mass balance considerations on the basis of the 28 CBs resulted in an estimation of a total storage of approximate 733±158 kg ∑CBs in the Oderhaff, Achterwasser, Greifswalder Bodden, Oder Rinne, Arkona Basin and Bornholm Basin in the past 65 years, covering the time period since CBs were first produced. Based on river data about 500 kg of ∑CBs were supplied during this time by river Oder, that may thus be the major source of these compounds for the southern Baltic Sea.

Description: The Labrador Current is part of the anticlockwise subpolar gyre and plays a major role in the formation of North Atlantic Deep Water. It is influenced by the West Greenland and Baffin currents supplying warmer Atlantic and cold polar waters, respectively. During the early Holocene, at the final stage of the last deglaciation, meltwater and iceberg discharge caused highly variable conditions in the Labrador Current. In order to assess its sensitivity to such freshening, this study provides a well-resolved Holocene paleoclimatic record from the Labrador Shelf. Based on benthic foraminiferal faunal and alkenone biomarker analyses, we differentiated four distinct climatic periods in the western Labrador Sea. From 8.9 to 8.6 ka BP, the Labrador Shelf was dominated by polar water outflow from Baffin Bay and covered by perennial sea ice. Between 8.6 and 7.4 ka BP, a strong subsurface inflow of warmer Atlantic water masses is ascribed to an intensification and redirection of the West Greenland Current. At 7.4 ka BP, the decreased influence of Atlantic water masses on the Labrador Shelf marks the establishment of winter convection leading to the formation of Labrador Sea Water in the central basin. Concurrently, an intensified polar water outflow through the Canadian Gateways strengthened the inner Labrador Current, and higher primary productivity suggests longer spring blooms because of a shorter sea-ice season during the Holocene Thermal Maximum. In the late Holocene after 3 ka BP, periodic fluctuations of primary productivity may tentatively be correlated with stronger and weaker northwesterly winds.

Description: Results of particle flux studies using sediment traps in the northeast Atlantic Ocean at 33oN, 22oW, a time-series station (L1/K276) operated within the German contribution to the international Joint Global Ocean Flux Study (JGOFS) between summer 1993 and summer 2001, are presented. The particle flux at 2000 m depth is highly seasonal with only one main peak in February and March and is characterized by strong interannual variability. The comparison of the particle flux time series with the measurements of chlorophyll and phaeopigments in the sediment trap material, and chlorophyll-a concentrations at surface from SeaWiFS together with the similarity of the pattern observed in the alkenone flux, particulate organic carbon (POC) and calcium carbonate (CaCO3) leads to the conclusion that the particle flux at this position is fast and directly coupled to the phytoplankton development and decay in the overlying euphotic zone. SeaWiFS chlorophyll-a data (1997-2001) and characteristics of the upper water column (mixed layer depth, depth of nitracline, primary production) as predicted by an eddy-permitting model of the North Atlantic coupled with a simple nitrate-phytoplankton-zooplankton-detritus (NPZD) pelagic-ecosystem model are used to understand the observed interannual differences in particle flux at 2000 m. Our results suggest that the interannual differences in the observed particle flux are a direct consequence of the variability of phytoplankton biomass and primary production in the euphotic zone in this region.