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  • Blackwell Publishing Ltd  (13)
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 42 (2004), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: This investigation was undertaken to develop an integrated method of downhole fracture characterization using a tracer. The method presented can be used to locate water-bearing fractures that intersect the well, to determine the ambient fracture flow rate and hydraulic head, and to calculate fracture transmissivity. The method was tested in two fractured crystalline bedrock wells located at the University of Connecticut in Storrs. The method entails injecting a tracer (uranine dye) into the well, while at the same time water is pumped out of the well. After steady-state conditions are reached, a borehole tracer concentration profile is developed. The dilution of the tracer is used to locate the inflowing fractures and to determine their flow rate. The fracture flow rate, plus the drawdown in the well, is then used to determine the fracture hydraulic head, transmissivity, and ambient flow rate.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Field tests were conducted to investigate skin effects in multilevel ground water samplers installed with direct push methods. Tests consisted of determining hydraulic conductivity values using slug tests in five multilevel samplers before, during, and after development. Development was conducted using a minisurge block tool designed for this study. Post-development hydraulic conductivity values were found to be 3.2 to 9.6 times greater than predevelopment values. The largest differences were observed in multilevel samplers positioned in low permeable materials that were installed in preprobed holes advanced by hydraulic hammering and pushing as opposed to probes situated in higher permeable materials that were installed in cored holes. The presence and magnitude of the skin effects, as well as the reduction of these effects by rigorous development, were confirmed through comparisons with steady-state pumping tests conducted in multilevel samplers and previously conducted slug tests in conventional monitoring wells. These results indicate the need for rigorous development prior to hydraulic conductivity testing in ground water samplers installed with direct push methods.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 15 (1995), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: A soil-gas survey was conducted at a gasoline service station and a former fire training facility to determine if surveying for hydrogen sulfide could be useful in locating nonaqueous phase hydrocarbon fuel in the subsurface. Relative; to total organic vapor, oxygen, and carbon dioxide distributions, detectable hydrogen sulfide concentrations were much more restricted to the suspected source vicinity at both sites. Appreciable levels of soil-gas hydrogen sulfide. up to 600 Vppb. were observed in areas characterized by anaerobic or microaerophilic conditions having bulk oxygen levels below 4 percent. Based on the hydrogen sulfide distribution, nonaqueous phase hydrocarbon fuel was located at each site. These results suggest that soil-gas surveying for hydrogen sulfide may help locale mobile or residual gasoline and other nonaqueous phase hydrocarbons in the subsurface.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 14 (1994), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: The vertical distribution and partitioning (between the solid and aqueous phase) of chromium in a glaciofluvial aquifer in northeastern Connecticut were assessed. Most of the chromium (99 percent of its mass) is bound to the soil. Retardation is primarily the result of binding to organic matter and adsorption to iron oxide coatings. However, other attenuation mechanisms also appear to be significant. If the degree of chromium binding observed here is representative of other chromium contaminated sites, pump-and-treat remediation will not remove the vast amount of chromium from the subsurface. However, most of the chromium may be immobile, and removal may not be required following the initial pumping to remove the mobile fraction. Further knowledge of the mechanisms that bind chromium to the soil, their reversibility, and their kinetics is essential to developing effective remediation strategies.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 19 (1999), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: “Contamination of heating oil with MTBE could result in increasing the environmental impact of subsurface heating oil releases.”
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 31 (1993), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: The field screening of soil gas CO2 and O2 using portable instruments is shown to be useful for indirectly detecting and delineating subsurface gasoline contamination. Shallow (〈 50 cm) soil gas surveys performed at a site of subsurface gasoline contamination in Connecticut indicated a good correlation between elevated CO2, depleted O2, and total hydrocarbon vapor anomalies. CO2 and O2 anomalies were also found to be spatially coincident with the area of known subsurface gasoline leakage. Soil gas CO2 levels ranged from 0.2 to 18.7 volume percent, whereas O2 levels ranged from 20.8 to 0.5 volume percent. The gases exhibited a nearly constant inverse correlation except near the source of contamination. In this area, CO2 generation from anaerobic degradation of hydrocarbons likely caused a decrease in the observed CO2 and O2 correlation. This suggests that the ratio of soil gas CO2 to O2 may be useful to delineate aerobic and anaerobic degradation zones, the latter being in the vicinity of highly contaminated areas. Periodic sampling of seven permanent soil gas probes over a 17-month period indicated significant seasonal variations in CO2 and O2. When the soil was warmest during the summer, the CO2 reached a maximum and O2 reached a minimum. The opposite was observed during the winter when the soil achieved its minimum temperature. These observations most likely reflect changes in microbial acitivity in response to subsurface temperature variations. Further, hydrocarbon vapor levels were observed to decrease by several orders of magnitude to nondetectable levels during the winter months. Although CO2 and O2 anomalies were also diminished during the winter months, they were still readily detectable. These observations indicate that soil gas surveying for subsurface gasoline leakage may be enhanced by monitoring CO2 and O2.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 27 (1989), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: An analytical transport model is presented for evaluating vertically averaged concentration data derived from purged and partially penetrating monitoring wells. The model is applicable to continuous contaminant emission from a finite source with longitudinal advection, and three-dimensional dispersion. The model is used to investigate how screened length may influence contaminant detection, mapping, and modeling. Sensitivity analyses suggest that contaminant concentrations determined from monitoring wells may underestimate the level of aquifer contamination, depending on screened depth, location of the well relative to the contaminant source, the vertical source dimension, and degree of vertical plume spreading. The magnitude of this effect may be comparable to, and in excess of, concentration biases related to construction materials and sampling procedures. Additional screened interval influences may include: underestimates of contamination extent and migration rate; apparent indications of attenuation processes and steady-state conditions; over- estimates of vertical contaminant spreading; increased time of contaminant detection; and poor transport model predictions, owing to well-biased concentration distributions.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 35 (1997), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Mathematical models that simulate common monitoring well sampling demonstrate the distortions that vertical concentration averaging causes during the mapping and modeling of an idealized, three-dimensional contaminant plume emanating from a simple source of constant solute concentration. The apparent extent of the plume, mapped using simulations of a regular grid of screened monitoring wells, ranged from a worst case of 0% of the original plume area for long screens (4 m) in a low-permeability formation to 90% for short screens (1 m) in a high-permeability formation. When well design and purging procedure were inconsistent among wells, the mapped plume exhibited spurious directional skewing, bifurcation, zones of low concentration, intermittent sources, or multiple sources. Although the study plume was not retarded, calibrating a transport model to the monitoring well data resulted in retardation factors of up to 23. If first-order decay was assumed, the apparent decay constant was found to be as much as 1.8 × 10-7 sec-1 (T1/2= 45 days). Apparent retardation or decay was inconsistent from well to well, depending on the saturated screen length, the degree of screen desaturation during purging, and the distance from the source. The study indicates that the quantitative assessment of contaminant distributions and transport processes requires discrete vertical sampling in the common situation where concentrations vary sharply with depth, even in the most ideal hydrogeologic environment. If screened monitoring wells are used, screen lengths and placements should be appropriate to the contamination situation being assessed and inherent biases must be considered. Even so, vertical concentration averaging biases and the resulting inconsistencies can result in highly misleading evaluations of ground-water contamination problems.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 36 (1998), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Conducting and interpreting slug tests in wells with screen sections and sand packs that span the water table are severely complicated by sand pack drainage and resaturation. Sand pack drainage greatly reduces the actual head difference between the well and the formation. Resaturation of the drained sand pack must be properly accounted for, or the formation hydraulic conductivity will be underestimated. The magnitude of error is a function of the well geometry, sand pack properties, and the model chosen to interpret the data. A method has been developed to correct for sand pack resaturation by calculating the specific yield of a drained sand pack using the early recharge data of a slug test. Slug tests were conducted in one well in which the water table varied over time, creating both partially and fully submerged screen and sand pack conditions for comparative testing. The mid-time, log-linear portion of slug test data was corrected using the calculated specific yield of the drained sand pack to yield essentially the same hydraulic conductivity value as the fully submerged screen results. Not accounting for sand pack resaturation would have yielded a hydrauli c conductivity value that was lower than the submerged screen results by a factor of seven.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: The objective of this study was to confirm if MTBE, which is not intentionally added to fuels other than gasoline, is a contaminant in heating oil and diesel fuel. The study entailed conducting a statewide sampling program of heating oil and diesel fuel in Connecticut. An analytical method was developed to conduct analyses of heating oil and diesel fuel for MTBE in the milligram per liter (mg/L) range. The method involved equilibrating product with water to extract MTBE followed by static head-space analysis on aliquots of the water. Analyses were conducted using a gas chromatograph with a MTBE specific column. The statewide sampling program confirmed the widespread occurrence of MTBE in heating oil and diesel fuel. MTBE was detected in all samples collected during our sampling program at concentrations ranging from 9.7 to 906 mg/L in heating oil (26 samples), and from 74 to 120 mg/L in diesel fuel (five samples). Based on these ranges. MTBE concentrations in ground water in the vicinity of heating oil and diesel fuel releases could exceed thousands of micrograms per liter. Our analysis would suggest that the levels of heating oil and diesel fuel contamination observed could result from the commingling of only a few parts gasoline with thousands of parts of these fuels. The extent to which MTBE occurs in heating oil and diesel fuel nationwide is not known, but our data suggests that it may be widespread.
    Type of Medium: Electronic Resource
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