ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Complex Chemistry of Reactive Organic Compounds, XXXIV. Incorporation of Diazomethane into Carbonylmanganese and -rhenium ComplexesReaction of pentacarbonylhydridomanganese (1a) and -rhenium (1b) with diazomethane leads via incorporation of the diazoalkane to the novel complexes Mn3(CO)12 (N2CH3) (3) and M2(CO)10 (N2CH2) (4a: M=Mn; 4b: M=Re), resp., which contain coordinatively stabilized diazomethane or the methanediazo moiety.
Notes:
Die Reaktionen von Pentacarbonylhydridomangan (1a) bzw. -rhenium (1b) mit Diazomethan führen unter Einbau des Diazoalkans zu den neuartigen Komplexverbindungen Mn3(CO)12 -(N2CH3) (3) sowie M2(CO)10 (N2CH2) (4a: M=Mn; 4b: M=Re), in denen Diazomethan bzw. die Methandiazo-Gruppierung komplexstabilisiert sind.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801130809
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