Keywords:
Ruthenium.
;
Chemistry, Inorganic.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (488 pages)
Edition:
1st ed.
ISBN:
9781617616174
Series Statement:
Chemical Engineering Methods and Technology
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=3018276
DDC:
546/.632
Language:
English
Note:
Intro -- RUTHENIUM: PROPERTIES, PRODUCTION AND APPLICATIONS -- RUTHENIUM: PROPERTIES, PRODUCTION AND APPLICATIONS -- LIBRARY OF CONGRESS CATALOGING-IN-PUBLICATION DATA -- CONTENTS -- PREFACE -- Chapter 1 LOW-TEMPERATURE THERMALLY-ACTIVATED PULSED CHEMICAL VAPOR DEPOSITION OF RUTHENIUM THIN FILMS USING CARBONYL-DIENE PRECURSOR -- Abstract -- Introduction -- 1. Pulsed CVD Equipment -- 1.1. Tool Design -- 1.2. Tool Features -- 1.2.1. Vacuum performance -- 1.2.2. Gas pulse shape and parameters -- 1.2.3. Role of MFC in pulsed deposition processes -- 1.3. Consecutive Pulsed CVD Process Options -- 1.3.1. Consecutive pulsed mode features -- 1.3.2. Evacuation steps in the process cycle -- 1.3.3. Process cycle duration and pulse length design -- 1.4. Temperature Conditions -- 2. Pulsed CVD Process Methodology -- 2.1. Pulsed CVD Process Cycle Design -- 2.2. Precursor and Sample Characterization -- 2.3. Typical Pulsed CVD Process Procedure -- 2.4. Ruthenium Thin Film Analysis -- 2.4.1. Ru thin film thickness measurements -- 2.4.2. Ru thin film properties studies -- 3. Ru Film Growth Kinetics on Silicon and Sio2 Surfaces -- 3.1. Ru Film Appearance and Growth vs Precursor Vapor Concentration -- 3.2. Ru Film Appearance and Growth vs Cycle Number -- 3.3. Ru Film Growth Kinetics vs Deposition Temperature -- 3.4. Ru Film Appearance and Growth vs Process Pressure -- 3.5. Ru Film Growth Kinetics vs Second Reactant -- 3.5.1. Single second reactant and MOCVD cases -- 3.5.2. Ru film growth kinetics vs second reactant sequence -- 3.6. Ru Film Growth in 3D Structures -- 3.7. Ru Film Growth Kinetics Features Summary -- 3.7. Importance of Nucleation for Ru Film Growth -- 4. Ru Nucleation Features -- 4.1. Samples for Nucleation Characterization and Evaluation Methodology -- 4.2. Ruthenium Film Nucleation and Growth on the Dielectric Layers.
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4.3. Ruthenium Film Growth on Metal Seed Layers -- 4.4. Ruthenium Film Growth in 3D Structures with Metal Seed Layers -- 4.5. Ru Film Surface Selectivity -- 4.6. Anomalous Features of Ru Film Nucleation and Growth -- 5. Ru Film Structure, Composition and Properties -- 5.1. Ruthenium Film Structure -- 5.1.1. Some specific types of ruthenium film appearance -- 5.1.2. Ru film structure studies -- 5.2. Ruthenium Film Composition -- 5.3. Ruthenium Film Properties -- 6. Schemes of Ru Film Growth -- 6.1. Brief Consolidation of Supported Data -- 6.2. Basic Concept of Ru Growth -- 6.3. Ruthenium Film Growth Schemes at Low Temperatures -- 6.4. Ruthenium Growth Schemes at High Temperatures -- 6.5. Ru Growth in Extremely Low-Temperature Region -- Conclusion -- Acknowledgment -- References -- Author biography -- Chapter 2 SELECTIVE HYDROGENATION OF UNSATURATED FUNCTIONAL GROUPS OVER HETEROGENEOUS RUTHENIUM CATALYSTS -- 1. Introduction -- 2. Selective Hydrogenation of Unsaturated Functional Groups -- 3. Hydrogenation Properties of Ruthenium Catalysts -- 3.1. Fischer-Tropsch Synthesis -- 3.2. Ammonia Synthesis on Ruthenium Catalysts -- 4. Selective HydrogenATION OF , -Unsaturated Aldehydes to , -Unsaturated Alcohols over Ruthenium Catalysts -- 4.1. Introduction -- 4.2. Some Words about Importance of Unsaturated Alcohols -- 4.3. Reaction Pathways in the Hydrogenation of Unsaturated Aldehydes -- 4.4. Factors Influencing Selectivity of Hydrogenation of Unsaturated Aldehydes to Unsaturated Alcohols -- 4.4.1. The effect of an organic compound structure -- 4.4.2. The effect of catalyst structure -- 4.4.2.1. The effect of ruthenium dispersion -- 4.4.2.2. The effect of support -- 4.4.2.3. The effect of second metal -- 5. Hydrogenation of Halogenated Aromatic Nitro Compounds to Halogenated Anilines -- 5.1. Introduction.
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5.2. Halogenated Anilines as Important Intermediates -- 5.3. Reaction Pathways in the Hydrogenation of Halonitrobenzenes -- 5.4. Chemical Methods of Reduction of Aromatic Halonitro Compounds -- 5.5. Ruthenium Catalysts in Hydrogenation of Halogenated Aromatic Nitro Compounds: Structure - Activity Relationships -- 5.5.1. The effect of the structure of organic compound molecule on the selectivity of hydrogenation of halonitroarenes to haloanilines -- 5.5.2. The effect of catalyst structure on the selectivity of hydrogenation of halonitroarenes to haloanilines -- 5.5.2.1. The effect of ruthenium dispersion -- 5.5.2.2. The effect of support and preparation procedure -- 5.5.2.3. The effect of additional metal -- Conclusions and Prospects for the Future -- Acknowledgments -- References -- Chapter 3 RACEMIZATION OF SECONDARY ALCOHOLS OVER HETEROGENEOUS RU-CATALYSTS -- 1. Introduction -- 1.1. Chemistry of Ruthenium -- 1.2. Ruthenium in Zeolites -- 1.3. Ruthenium Complexes -- 1.4. Heterogeneous Ruthenium Catalysts -- 1.5. One-Pot Syntheses -- 1.5.1. One-Pot systhesis of (R)-1-phenylethylacetate starting from acetophenone hydrogenation -- 1.5.2. Shvo´s catalyst -- 1.6. Dynamic Kinetic Resolution -- 1.6.1. DKR with Shvo's Catalyst -- 3.3. Racemization Catalysts -- 3.3.1. Influence of Ru concentration -- 3.3.2. Influence of Ru oxidation state -- 3.3.3. Reuse of Ru catalysts in the racemization of secondary alcohols -- 3.4. Influence of Solvents in the Racemization of Secondary Alcohols -- 3.5. Influence of Acyl Donor in the Racemization of Alcohol -- 3.6. Reaction Mechanism -- Conclusions -- Acknowledgment -- References -- Chapter 4 CATALYSIS BY RUTHENIUM HALO, OXO AND PORPHYRIN COMPLEXES -- Abstract -- 1. Introduction -- 1.1. Microdetermination of Ruthenium(III) and Applications of Ruthenium Complexes -- 2. Ruthenium Catalyzed Reactions.
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2.1. Metathesis and Polymerization -- 2.2. Hydrogenation and Dehydrogenation -- 2.3. Oxidation -- 2.4. Complex Formation/Cyclization -- 2.5. Ruthenium Porphyrin -- Conclusion -- References -- Chapter 5 RUTHENIUM COMPLEXES CONTAINING IMINOPHOSPHORANE LIGANDS: SYNTHESIS, STRUCTURE, REACTIVITY AND APPLICATIONS -- Abstract -- Introduction -- Ruthenium Complexes Containing Mixed Iminophosphorane-Phosphine Ligands -- Ruthenium Complexes Containing Methanide and Methandiide Anions Derived from Bis(Iminophosphorane)Methane Ligands -- Ruthenium Complexes Containing other Iminophosphorane-Based Ligands -- Conclusions -- Acknowledgments -- References -- Chapter 6 RUTHENIUM CARBONYL COMPLEXES: SYNTHESIS AND CATALYTIC HYDROGENATION REACTIONS -- Abstract -- Introduction -- Ruthenium Catalysed Hydrogenation and Tranfer Hydrogenation Reactions -- Chemoselective Hydrogenation With Molecular Hydrogen (H2) -- Transfer Hydrogenation Reactions -- Enantioselective Hydrogenation Reactions -- Conclusion -- References -- Chapter 7 RUTHENIUM COMPLEXES AS PHOTOSENSITIZERS: NEW POSSIBILITIES IN PHOTODYNAMIC THERAPY -- I. Abstract -- II. Introduction -- Photodynamic Therapy (PDT) -- Ruthenium(II) Polypyridyl Photosensitizers -- Interactions of DNA and Ruthenium Complexes -- Ruthenium in Medicine -- III. Monometallic Ruthenium Complexes -- IV. DNA Interactions with Multi-metallic Ruthenium Complexes -- V. Porphyrin-Ruthenium Complexes in PDT -- References -- Chapter 8 RUTHENIUM COMPLEXES FOR PHYSIOLOGY RESEARCH -- Abstract -- Introduction -- Ruthenium Complexes as Fluorescent Probes -- Nucleic Acid Nickers, Cutters, and Antitumoral Drugs -- Subcellular Localization Strategies -- Labeling Specific Proteins -- Ruthenium Complexes as Phototriggers -- Exquisite Control: Neurobiology Applications -- Further Applications -- Conclusion -- References.
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Chapter 9 RUTHENIUM THIOSEMICARBAZONE COMPLEXES -- 1. Introduction -- 2. Ligands -- 2.1. Bidentate Ligands -- 2.1.1. Benzaldehyde Thiosemicarbazone (BzTSC) Complexes -- 2.1.2. Thiophen-2-Aldehyde Thiosemicarbazone Complexes -- 2.1.3. Acetophenone Thiosemicarbazone Complexes -- 2.1.4. Anthracene-9-Aldehyde Thiosemicarbazone Complexes -- 2.2. Tridentate Ligands -- 2.2.1. Salicylaldehde Thiosemicarbazone Complexes -- 2.2.2. Pyridine-2-Aldehyde Thiosemicarbazone (PyTSC) and 2-Acetylpyridine Thiosemicarbazone Complexes (AcPyTSC) -- 2.2.3. Dehydroacetic Acid Thiosemicarbazones Complexes -- 2.3. Tetra Dentate Ligands -- 2.3.1. 2,6 Diacetylpyridine Mono(4-(4-Tolyl)Thiosemicarbazone) -- Conclusions -- Acknowledgments -- References -- Chapter 10 RUTHENIUM-CATALYSIS FOR OXIDATIVE CLEAVAGE OF OLEIC ACID DERIVATIVES -- Abstract -- Introduction -- I. Indirect Oxidations -- A. Synthesis of Epoxy, Diol, Ketol, Diketone Compounds -- B. Cross-Metathesis of Oleic Acid -- II. Catalytic Oxidative Systems for Oleic Acid Derivatives Cleavage -- A. Ru / NaOCl -- B. Ru / Peracid -- C. Ru / NaIO4 -- III. Oleic Acid Acid Cleavage by Rucl3 / Naio4 under Ultrasonic Irradiation -- A. Sonochemistry -- B. Oleic Acid Oxidation in Water -- C. Optimization of Oleic Acid Oxidative Cleavage -- D. Synergy Aliquat® 336 and Ultrasound for the Oxidative Cleavage of Oleic Acid with 2% Rucl3 / 4.1equiv Naio4 - H2o/Mecn Ratio 1:1 -- E. Comparison between Catalyst Amounts for Oleic Acid Cleavage -- VI. Oxidative Cleavage Mechanisms -- Conclusion -- References -- Chapter 11 A REUSABLE POLYMER ANCHORED RUTHENIUM (II) COMPLEX CATALYST FOR THE REDUCTIVE CARBONYLATION OF NITROAROMATICS -- Abstract -- Introduction -- Experimental -- Carbonylation Procedure -- Preparation of Catalyst -- Preparation of P-Bromopolystyrene (2).
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Preparation of Lithiated Polystyrene (3) and Polymer Anchored Phenylpyridine (4).
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