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  • 1
    Publication Date: 2024-03-25
    Description: In this dataset, we present Fe, Na and Ca concentration and fluxes retrieved from the North Greenland Eemian Ice Drilling (NEEM) ice core project, covering the last 108 kyrs. The sampling resolution was 110 cm. To ensure an effective dissolution of Fe particles, samples were acidified to pH 1 using Suprapure nitric acid and stored at room temperature for 1 month before the analysis. The ice samples were analyzed with an Inductively Coupled Plasma Single Quadrupole Mass Spectrometer equipped with a quartz Scott spray chamber. Limits of Detection, calculated as three times the standard deviation of the blanks, were 0.8 µg L-1 for 57Fe, 1 µg L-1 for Ca and 3 µg L-1 for Na. Our results show that Holocene Fe fluxes (0.042 -11.7 kyr b2k, 0.5 mg m-2 yr-1) at the NEEM site were four times lower than the average recorded over the last glacial period (11.7– 108 kyr b2k, 2.0 mg m-2 yr-1), while they were greater during the Last Glacial Maximum (LGM, 14.5 – 26.5 kyr b2k, 3.6 mg m-2 yr-1) and Marine Isotope Stage 4 (MIS 4, 60 - 71 kyr b2k, 5.8 mg m-2 yr-1).
    Keywords: Age; Calcium; Calcium, flux per year; Calculated; Depth, bottom/max; DEPTH, ice/snow; Depth, top/min; Greenland; high-resolution; Ice core; ICEDRILL; Ice drill; iron; Iron; Iron, flux per year; NEEM; North Greenland Eemian Ice Drilling; Sodium; Sodium, flux per year
    Type: Dataset
    Format: text/tab-separated-values, 14386 data points
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  • 2
    Publication Date: 2023-06-21
    Description: Iodine has a significant impact on promoting the formation of new ultrafine aerosol particles and accelerating tropospheric ozone loss, thereby affecting radiative forcing and climate. Therefore, understanding the long-term natural evolution of iodine, and its coupling with climate variability, is key to adequately assess its effect on climate on centennial to millennial timescales. Here, using two Greenland ice cores (NEEM and RECAP), we report the Arctic iodine variability during the last 127,000 years. We find the highest and lowest iodine levels recorded during interglacial and glacial periods, respectively, modulated by ocean bioproductivity and sea ice dynamics. Our sub-decadal resolution measurements reveal that high frequency iodine emission variability occurred in pace with Dansgaard/Oeschger events, highlighting the rapid Arctic ocean-ice-atmosphere iodine exchange response to abrupt climate changes. Finally, we discuss if iodine levels during past warmer-than-present climate phases can serve as analogues of future scenarios under an expected ice-free Arctic Ocean. We argue that the combination of natural biogenic ocean iodine release (boosted by ongoing Arctic warming and sea ice retreat) and anthropogenic ozone-induced iodine emissions may lead to a near future scenario with the highest iodine levels of the last 127,000 years.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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