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  • 1
    Publication Date: 2022-03-15
    Description: The origin of magmatic fluids along the East African Rift System (EARS) is a long-lived field of debate in the scientific community. Here, we investigate the chemical composition of the volcanic gas plume and fumaroles at Nyiragongo and Nyamulagira (Democratic Republic of Congo), the only two currently erupting volcanoes set on the Western Branch of the rift. Our results are in line with earlier conceptual models proposing that volcanic gas emissions along the EARS mainly reflect variable contributions of either a Sub-Continental Lithospheric Mantle (SCLM) component or a Depleted Morb Mantle (DMM) component, and deeper fluid. At Nyiragongo and Nyamulagira, our study discards a major contribution of a high 3He/4He mantle plume component in the genesis of volcanic fluids beneath the area. High CO2/3He in fumaroles of both volcanoes is thought to reflect carbonate metasomatism in the lithospheric mantle source. As inferred by previous results obtained on the lava chemistry, this carbonate metasomatism would be more pronounced beneath Nyiragongo. This supports the idea of the presence of distinct metasomes within the lithospheric mantle beneath the Western Branch of the rift.
    Description: Published
    Description: 120811
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: East African Rift System ; Volcano ; Gas chemistry ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2021-12-13
    Description: Here we introduce the updated, interactive and open-access database for African volcanic lakes, country by country. The previous database VOLADA (VOlcanic LAke DAta Base, Rouwet et al., 2014) reported 96 volcanic lakes for Africa. This number is now revised and established at 220, converting VOLADA_Africa 2.0 in the most comprehensive resource for African volcanic lakes: 81 in Uganda, 37 in Kenya, 33 in Cameroon, 28 in Madagascar, 19 in Ethiopia, 6 in Tanzania, 2 in Rwanda, 2 in Sudan, 2 in D.R. Congo, 1 in Libya, and 9 on the minor islands around Africa. We present the current state-of-the-art of arguably all the African volcanic lakes that the global experts and regional research teams are aware of, and provide hints for future research directions, with a special focus on the volcanic hazard assessment. All lakes in the updated database are classified for their genetic origin and their physical and chemical characteristics, and level of study. The predominant rift-related volcanism in Africa favors basaltic eruptive products, leading to volcanoes with highly permeable edifices (e.g. scoria), and hence less-developed hydrothermal systems. Basal aquifers accumulate under large volcanoes and in rift depressions providing a potential scenario for phreatomagmatic volcanism. This hypothesis, based on a morphometric analysis and volcanological research from literature, conveys the predominance of maar lakes in large monogenetic fields in Africa (e.g. Uganda, Cameroon, Ethiopia), and the absence of high-activity crater lakes, generally found at arc-volcanoes. Considering the large number of maar lakes in Africa (172), within similar geotectonic settings and meteoric conditions as in Cameroon, it is somewhat surprising that “only” from Lake Monoun and Lake Nyos fatal CO2 bursts have been recorded. Explaining why other maars did not erupt in such fashion is a question that can only be answered by enhancing insights into physical limnology and fluid geochemistry of the so far poorly studied lakes. From a hazard perspective, there is an urgent need to tackle this task as a community.
    Description: Published
    Description: 717798
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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  • 3
    Publication Date: 2022-06-22
    Description: An integrated approach using chemical and microbial indicators has been tested in two different sites of the Campania Plain (Southern Italy) with different land use covering and different hydrogeological features in order: (1) to define the water-rock interaction processes, (2) to differentiate sources of pollution in a detailed way (3) to evaluate the degree of water quality in the studied alluvial aquifer and (4) to identify the most worrying elements for human's health. Groundwater have showed a HCO3-Ca signature for both investigated sites, and a progressive enrichment in alkali ions has been highlighted moving from the boundary of the plain toward the coastal areas, due to groundwater interaction with volcanic rocks along the flow path. The application of the Factor Analysis allowed to identify different sources of pollution, which were attributed to (a) leaks in the sewer system for the Agro-Aversano Area and also the spreading of manure as fertilizers in agricultural activities for the Caiazzo Plain. Furthermore, it has been highlighted that the use of major elements, trace elements and microbiological indicators, allows to accurately differentiate contamination processes in progress. In fact, from the results of the Factor Analysis applied in the Agro-Aversano area, no significant statistically relationships between major elements and microbiological indicators of fecal contamination were highlighted, unlike the Caiazzo plain where statistically significant correlations have been found between major and trace elements and microbiological indicators. The use of a Groundwater Quality Index has shown general poor water quality for the majority of analyzed samples due to the high amount of Nitrate and Fecal indicators. The use of a Health Risk Assessment highlighted that Nitrate coupled with Fluoride represent the most important concern for human health compared to the all investigated parameters in both sites.
    Description: Published
    Description: 2083–2099
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: Alluvial aquifer; Factor analysis; Fecal pollution; GQI; HRA; Trace elements
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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  • 4
    Publication Date: 2022-06-22
    Description: Geothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them are found along the coast and thus, water is often saline due to marine intrusion. In the current study, we present about 300 unpublished and literature data from thermal and cold mineral waters collected along Greece. Samples were analysed for major ions, Li, SiO2 and isotopes in water. Measured temperatures range from 6.5 to 98°C, pH from 1.96 to 11.98, whilst Total Dissolved Solutes (TDS) from 0.22 to 51 g/L. Waters were subdivided into four main groups: i) thermal; ii) cold; iii) acidic (pH 〈5) and iv) hyperalkaline (pH 〉11). On statistical basis, the thermal waters were subdivided into subgroups according to both their temperature [warm (〈29 °C), hypothermal (29-48 °C), thermal (48-75 °C) and hyperthermal (〉75 °C)] and TDS [low salinity (〈4 g/L), brackish (4-30 g/L) and saline (〉30 g/L)]. Cold waters were subdivided basing on their pCO2 [low (〈0.05 atm), medium (0.05-0.85 atm) and high (〉0.85 atm)]. δ18O-H2O ranges from -12.7 to +2.7 ‰ vs. SMOW, while δ2H-H2O from -91 to +12 ‰ vs. SMOW being generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Positive δ18O shifts with respect to the former are mostly related to mixing with seawater, while only for a few samples they point to high-temperature water-rock interaction processes. Only a few thermal waters gave reliable geothermometric estimates, suggesting reservoir temperatures between 80 and 260 °C.
    Description: Published
    Description: 2111–2133
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Hydrogeochemistry ; Stable isotopes ; Carbon dioxide ; Geothermometry ; 03. Hydrosphere ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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