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  • 1995-1999  (9)
  • 1999  (4)
  • 1995  (5)
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 117 (1995), S. 615-623 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 117 (1995), S. 1888-1899 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 225-233 
    ISSN: 1434-1948
    Keywords: Arene complexes ; Chromium ; Sidechain functionalization ; Allenes ; Cuprates ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The cuprate addition to (arene)Cr(CO)3-substituted phosphorylallenes 1 gives rise to the regioselective formation of complexed allylphosphane oxide derivatives 3a-c and allylphosphonate derivatives 3d-j in good yields. In the case of racemic planar chiral ortho-substituted complexed (arylallenyl)phosphonates 1c, d the protonation of the intermediate allyl anion proceeds diastereoselectively due to the hindered rotation around the Cipso-Cα bond. This diastereoselective protonation is discussed on the basis of the conformational analysis as deduced from the X-ray structure analyses of the allenylphosphonate 1d and the allylphosphonates 3i, j.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 42 (11-12). pp. 2113-2126.
    Publication Date: 2017-07-10
    Description: In the Neil Brown Instruments' MKIIIB-CTD (conductivity-temperature-depth profiler), the system's digital outputs for the three basic measurements of temperature, conductivity and pressure typically show some small amplitude deviations from smooth calibrations which should be corrected for to achieve high accuracies, as required, e.g. within the Hydrographic Program (WHP) of the current World Ocean Circulation Experiment (WOCE). These deviations show up as (i) a strong nonlinearity or even discontinuity of several mK close to 0°C in temperature output leading to too high subzero temperatures; (ii) a jump of order 0.002 mS cm−1 in conductivity output when passing the half-range value 32.768 mS cm−1, which causes jumps in the relation of potential temperature and salinity; and (iii) errors in pressure measurements of up to 4 dbar due to mechanical hysteresis and both static and dynamic responses to temperature changes. The existence of these effects is demonstrated, and methods to reduce the associated errors are suggested.
    Type: Article , PeerReviewed
    Format: text
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  • 5
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    Oceanography Society
    In:  Oceanography, 8 (3). pp. 87-91.
    Publication Date: 2018-08-15
    Description: First Paragraph: From its littoral margin to the open ocean, the western South Atlantic (Fig. 1) is marked at all depths by circulation patterns and exchange processes that are centrally important to the regional marine resources and local economies, and to the global flux of heat and dissolved substances. Among other important characteristics, the Southwest Atlantic (SWA) is characterized by the presence of the Brazil Current (BC), a warm western boundary current that, while weaker than the Gulf Stream in terms of mass transport, is energetically comparable to its North Atlantic counterpart, particularly in the region of confluence with the northward-flowing Malvinas Current (MC) at approximately 38°S. Because of the wide range of issues needed to be understood in terms of the physical oceanography, this oceanic region has been addressed by several important scientific programs, a few of which are listed in Table 1 and indicated on Fig. 2. Results from these and other programs are summarized here and recommendations for future efforts are offered.
    Type: Article , PeerReviewed
    Format: text
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  • 6
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    Sears Foundation of Marine Research
    In:  Journal of Marine Research, 53 (6). pp. 929-957.
    Publication Date: 2017-11-28
    Description: Two high-resolution hydrographic sections occupied during February, March 1989 in the western and eastern basins of the North Atlantic at 14.5N are combined to study the water mass structure and meridional mass and heat transports. Absolute velocities were determined using these data and an earlier section at 8N in a linear inverse analysis. Mass balance for several layers representing the main water masses in the region and a zero net divergence for the sum of geostrophic and Ekman transport between the two sections are assumed. Using the annual mean of Ekman transports (13.6 Sv, 14.5N), (15.2 Sv, 8N) based on the climatology by Isemer and Hasse (1985) the annual average fluxes for the sections at 8N and 14.5N have been calculated. For the annual mean the strength of the meridional overturning cell at 14.5N amounts to 15.9 Sv with an associated heat transport of 1.22 PW. A similar value can be obtained at 8N where the annual mean heat transport reaches 1.18 PW and the overturning cell measures 15 Sv. The total northward heat transport is strongly dominated by the wind-driven Ekman heat transport. 'In-situ' values of heat transport using the actual wind-driven transports for the respective months yield even higher estimates. Heat transport at 14.5N rises to 1.37 +/- 0.42 PW (February) and the maximum is now at the 8N section, 1.69 +/- 0.52 PW (May). Comparisons of our results with another tropical section at 11N occupied concurrently demonstrate the large variability in heat transport related to changes in the wind field. Due to extremely weak winds in the eastern Atlantic and a resulting low Ekman transport, the 'in-situ' value of heat transport through this section ranged between 0.30 +/- 0.18 PW and 0.59 +/- 0.18 PW depending on the value chosen for the Ekman transport. The lower of the two heat transport estimates results from calculations with the actual observed winds and the other using a monthly climatological mean. That even the computations with the climatological monthly mean give such a low heat transport points to additional changes in the baroclinic structures between 11N and 14.5N.
    Type: Article , PeerReviewed
    Format: text
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  • 7
    Publication Date: 2017-05-31
    Type: Article , NonPeerReviewed
    Format: text
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  • 8
    Publication Date: 2016-06-23
    Type: Report , NonPeerReviewed
    Format: text
    Format: text
    Format: text
    Format: text
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  • 9
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    Wiley-VCH
    In:  In: Methods of Seawater Analysis. , ed. by Grasshoff, K., Kremling, K. and Ehrhardt, M. Wiley-VCH, Weinheim, New York, Chiester, Brisbane, Singapore, Toronto, pp. 41-73. 3rd completely rev. and extended ed
    Publication Date: 2012-07-18
    Type: Book chapter , PeerReviewed
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