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  • 1
    Online Resource
    Online Resource
    UiTM Press, Universiti Teknologi MARA ; 2022
    In:  Journal of Mechanical Engineering Vol. 19, No. 1 ( 2022-01-15), p. 71-82
    In: Journal of Mechanical Engineering, UiTM Press, Universiti Teknologi MARA, Vol. 19, No. 1 ( 2022-01-15), p. 71-82
    Abstract: In this study, polyurethane grouting materials (PUG) were prepared using two different types of polyol which were castor-based polyol (CPUG) and petrochemical-based polyol (PPUG). Four different ratios of polyol (OH) to isocyanate (NCO) were used in this study. The effect of different compositions of Isocyanate on mechanical properties were investigated and compared. The flexural strength, and compression strength shows the increment with the increase of the NCO composition. Optimum flexural strength, flexural modulus, and compression strength obtained at composition of PPUG4 and CPUG4 with the ratio of NCO: OH, 2.6: 1. PPUG gives a higher value of mechanical strength as compared to CPUG, however, results obtained for both types of polyurethane are in the range of industrial PU grouting properties grade. The decrease in cell wall of CPUG and PPUG with the increase of NCO:OH indicating the increment in cell wall interaction resulting higher mechanical properties of PUG.
    Type of Medium: Online Resource
    ISSN: 1823-5514 , 2550-164X
    URL: Issue
    Language: Unknown
    Publisher: UiTM Press, Universiti Teknologi MARA
    Publication Date: 2022
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  • 2
    In: Macromolecular Symposia, Wiley, Vol. 407, No. 1 ( 2023-02)
    Abstract: Graphene oxide (GO) is an oxidized form of graphene, laced with oxygen‐containing groups. In recent years, the cost‐effective and efficient synthesis of GO remains a significant issue. Hummer's method has become popular due to its simple top‐down synthesis, however, there is an issue due to the release of nitrate gaseous which is harmful to the environment. This research is carried out using regenerated carbon from waste tire as a source of synthesize process through the Hummers Method (HM) and Improved Hummers Method (IHM). The Raman peaks of IHM GO show that the D band and G band are at 1369.12 and 1583 cm −1 , respectively and the intensity ratio of the D band relative to the G band (ID/IG) is 0.84. The morphology and structure of graphene oxide show that a nanosize particle stalked together on the surface of the sample structure, bumping pieces, and a coarse surface. The elemental composition of carbon (C) is higher than the oxygen (O) element which showed a good composition of graphene oxide. The XRD spectroscopy indicates the crystal structure of the material and the interlayer spacing between the material and atoms. In this study, the improved method is used by replacing sodium nitrate (NaNO 3 ) with phosphoric acid (H 3 PO 4 ) during the synthesis process to help increase interlayer distance and helps oxidation on the basal planes. This result confirms that the graphene oxide can be synthesized from regenerated carbon from waste tire using an improved Hummer's method.
    Type of Medium: Online Resource
    ISSN: 1022-1360 , 1521-3900
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 2038549-3
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