In:
Angewandte Chemie, Wiley, Vol. 127, No. 23 ( 2015-06), p. 7022-7025
Abstract:
Reported herein is the rhodium‐catalyzed enantioselective CH bond silylation of the cyclopentadiene rings in Fe and Ru metallocenes. Thus, in the presence of ( S )‐TMS‐Segphos, the reactions took place under very mild conditions to afford metallocene‐fused siloles in good to excellent yields and with ee values of up to 97 %. During this study it was observed that the steric hindrance of chiral ligands had a profound influence on the reactivity and enantioselectivity of the reaction, and might hold the key to accomplishing conventionally challenging asymmetric CH silylations.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v127.23
DOI:
10.1002/ange.201502548
Language:
German
Publisher:
Wiley
Publication Date:
2015
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514305-6
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505872-7
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1479266-7
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505867-3
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506259-7
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